Building up nanostructured layer-by-layer films combining reduced graphene oxide-manganese dioxide nanocomposite in supercapacitor electrodes

• Published in: Thin solid films 2021-01, Vol.718, p.138483, Article 138483
• Main Authors: Oliveira, Danilo A., Lutkenhaus, Jodie L., Siqueira, José R.
• Format: Article
• Language: English
• Subjects: Energy storage; Layer-by-layer deposition; Manganese dioxide nanostructures; Nanostructured films; Reduced graphene oxide; Supercapacitors
• ISSN: 0040-6090; 1879-2731
• DOI: 10.1016/j.tsf.2020.138483

•Incorporation of MnO2 nanostructures into reduced graphene oxide (rGO) sheets.•rGO-MnO2 nanostructured layer-by-layer (LbL) film for supercapacitor application.•Areal capacitance with an order of magnitude higher (mF/cm2) than usual.•High capacitive retention performance of 99% and high charge-discharge time.•Superior performance compared with other reported rGO-MnO2 systems. Research on nanocomposites is essential to achieve supercapacitors with enhanced performance for energy storage. In that regards, carbon materials and metal oxides have been employed in conjunction to yield supercapacitors with improved properties. Here we present the fabrication of a layer-by-layer (LbL) film containing manganese dioxide (MnO2) nanostructures embedded into reduced graphene oxide (rGO) sheets and arranged with poly(allylamine-hydrochloride) (PAH) for supercapacitor application. While scanning electron microscopy images confirm the incorporation of MnO2 nanostructures into the rGO layers, cyclic voltammetry and galvanostatic charge-discharge measurements reveal the electrocapacitive features of the films. Nanostructured PAH/rGO-MnO2 LbL films containing 20 bilayers lead to a supercapacitor with high areal capacitance of ca. 112 mF/cm2 at 1 mV/s and 460 F/g at 1 A/g, in addition to a high capacitive retention performance of 99% over 10,000 cycles and a high charge-discharge time of ca. 600 s. Such properties demonstrate, therefore, the PAH/rGO-MnO2 LbL film a promising architecture to be further explored in energy storage nanostructured systems.