Municipal solid waste incineration fly ash to produce eco-friendly binders for sustainable building construction

• Published in: Waste management (Elmsford) 2021-02, Vol.120, p.114-124
• Main Authors: Marieta, Cristina, Guerrero, Ana, Leon, Iñigo
• Format: Article
• Language: English
• Subjects: Carbon; Chemical composition; Chloride; Cities; Coal Ash - analysis; Eco-cements; Incineration; Metals, Heavy - analysis; MSWI fly ash; Particulate Matter; Pozzolanic activity; Refuse Disposal; Solid Waste - analysis
• ISSN: 0956-053X; 1879-2456
• DOI: 10.1016/j.wasman.2020.11.034

•Waste incinerator fly as raw material to manufacture binders for construction.•Hydrothermal process activates fly ash pozzolanic reaction and dissolve chloride.•Fly ash to produce belite cements, low burning temperature and low CO2 emission. Municipal solid waste incinerator (MSWI) fly ash is a residue of municipal solid waste incineration whose recycling is currently a worldwide problem. Therefore, considerable efforts are being made to establish effective recovery techniques so MSWI can be used as a substitute for natural resources in construction, as in masonry blocks, roads and so on, or in the manufacture of new materials. MSWI fly ashes contain elements such as Ca, Si and Al, which make it possible for them to be used as raw material to manufacture cements. This paper presents the results obtained from the physicochemical characterization of two MSWI fly ashes from two Spanish cities. The research aims to explore the feasibility of using MSWI fly ash as raw material for sintering belite cements. The results show that MSWI fly ashes have a suitable composition. However, appropriate pre-treatment will be required to eliminate chloride and possible traces of heavy metals and to improve pozzolanic activity. Furthermore, the addition of vitreous silica in the proper proportions is required. The phases generated after calcination of the blend at 800 °C are not those corresponding to pure belite cements. Nevertheless, the possibility of using these ashes as supplementary cementitious material in the manufacture of eco-cements should be contemplated.