Pt/Pd and I/Br Isostructural Exchange Provides Formation of C–I···Pd, C–Br···Pt, and C–Br···Pd Metal-Involving Halogen Bonding

Complexes trans-[MCl2(NCNMe2)2] (M = Pt 1, Pd 2) were cocrystallized with CHBr3 and CHI3, forming 1:2 adducts isomorphic with previously reported trans-[PtCl2(NCNMe2)2]·2CHI3. In all cases, the C–X···M (X = Br, I; M = Pd, Pt) metal-involving halogen bonding together with numerous chloride-halomethan...

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Bibliographic Details
Published in:Crystal growth & design 2018-10, Vol.18 (10), p.5973-5980
Main Authors: Baykov, Sergey V, Dabranskaya, Uladzislava, Ivanov, Daniil M, Novikov, Alexander S, Boyarskiy, Vadim P
Format: Article
Language:English
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