Experimental Study on the Effect of Wax Crystal-Water Droplet Aggregations on Wax Deposition of Water-in-Oil Emulsions

• Published in: Energy & fuels 2023-02, Vol.37 (3), p.1940-1948
• Main Authors: Ma, Qianli, Wang, Chuanshuo, Lu, Yingda, Lei, Yun, Liu, Yang, Lv, Xiaofang, Zhou, Shidong, Gong, Jing
• Format: Article
• Language: English
• Subjects: Fossil Fuels
• ISSN: 0887-0624; 1520-5029
• DOI: 10.1021/acs.energyfuels.2c03764

Wax deposition in waxy crude oil emulsions remains a flow assurance challenge in offshore production. Wax molecular diffusion driven by the positive temperature gradient from the liquid to the pipe wall has been widely studied and regarded as the primary wax deposition mechanism; however, a considerable wax deposit of emulsions at a zero-temperature difference was detected, in which condition molecular diffusion is not likely to occur, suggesting there were other mechanisms that contribute to wax deposition. In this work, the wax deposition mechanism of water-in-oil emulsions at a zero-temperature difference was explored by a cold finger apparatus regarding the role of wax crystals and water droplets on wax deposition. Through microscopy observation and component measurement of deposits, the wax deposition mechanism, namely, wax crystal-water droplet aggregation formation and adhesion behavior, was proposed. During wax deposition, wax crystals in the emulsion interacted with water droplets, organizing the basic structure of aggregation. The liquid oil phase was entrapped at the inner space of the aggregation and entrained by the wax crystal-water droplet structure to generate a wax deposit. The formation of wax crystal-water droplet aggregations depends on the experimental temperature, where a larger size of aggregations that formed at a lower temperature preferred to yield a thicker deposit under the same stirring speed, while for the same temperature operation conditions, the medium and low speed promoted the adhesion behavior of the aggregations to the cold finger resulting in an increase in deposits; however, the high stirring condition sloughed off the formed deposits, reducing the deposit mass. The findings denote that the presence of wax crystal-water droplet aggregations in emulsion should be considered when describing the wax deposition process at low temperatures.