Hydrogenation of Olefins in Bitumen-Derived Naphtha over a Commercial Hydrotreating Catalyst

• Published in: Energy & fuels 2018-05, Vol.32 (5), p.6167-6175
• Main Authors: Xin, Qin, Alvarez-Majmutov, Anton, Dettman, Heather D, Chen, Jinwen
• Format: Article
• Language: English
• ISSN: 0887-0624; 1520-5029
• DOI: 10.1021/acs.energyfuels.8b00344

Instability associated with the presence of olefins in bitumen that is thermally processed during partial upgrading is a major concern for pipeline transportation and downstream refining. A common strategy for stabilizing thermally processed oils is to selectively hydrogenate the olefin-rich fractions, typically, the naphtha fraction (IBP–204 °C). In this paper, olefin hydrogenation was studied with hydrotreated bitumen-derived naphtha spiked with five model olefin compounds under mild hydrotreating conditions. The hydrogenation reactivities of the five model olefin/diolefin compounds are ranked in the order 1,3-hexadiene > allylbenzene > 1-heptene > 2-methyl-2-pentene > 1-methyl-cyclopentene. The reactivity is largely determined by the position of the double bond, and, to a lesser extent, by the molecular structure of the olefin. The conjugated diolefin, 1,3-hexadiene, was the most reactive. The two terminal olefins, 1-heptene and allylbenzene, were observed to be more reactive than the two olefins with internal double bonds: 2-methyl-2-pentene and 1-methyl-cyclopentene. Results also show that temperature has a significant effect on olefin hydrogenation performance, with the pressure and the liquid hourly space velocity having relatively moderate effects. Meanwhile, flash calculations confirmed the presence of vapor–liquid equilibrium under the operation conditions used. When the reactor temperature is 150 °C or less, reactions primarily occur in the liquid phase, whereas at temperatures of 200 °C or higher, the reactions occur in the vapor phase. A hydrogenation kinetics model is proposed that successfully describes the observed trends of olefin hydrogenation in the liquid phase.