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Highly Selective Electrooxidation of Urea to Nitrogen on Copper/Nickel Boride Interface under Alkaline Condition

Urea electrooxidation reaction (UOR) plays an important role in environmental protection and energy regeneration. The extensively studied nickel-based catalysts exhibit good activity for UOR, but urea is more prone to be overelectrooxidized to another pollutant NO x – (x = 2, 3). Herein, the Cu/Ni-B...

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Bibliographic Details
Published in:Industrial & engineering chemistry research 2023-06, Vol.62 (22), p.8736-8743
Main Authors: Shen, Zhichao, Qi, Yanbin, Ge, Wangxin, Jiang, Hongliang, Li, Chunzhong
Format: Article
Language:English
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Summary:Urea electrooxidation reaction (UOR) plays an important role in environmental protection and energy regeneration. The extensively studied nickel-based catalysts exhibit good activity for UOR, but urea is more prone to be overelectrooxidized to another pollutant NO x – (x = 2, 3). Herein, the Cu/Ni-B interface catalyst is presented. The introduction of Cu significantly enhances the Faradaic efficiency of N2 (nearly 70% at 1.70 V versus RHE). Electrochemical tests and in situ Raman spectroscopy results show that the introduction of Cu significantly affects the density of OH* species on the catalyst in the UOR process. It is proposed that with a moderate decrease in OH* density, the catalyst can provide enough sites for urea molecules to allow simultaneous adsorption of the two N atoms, facilitating the process of N-N coupling to form N2. This work is also instructive for the design of electrocatalysts for other nucleophile electrooxidation reactions.
ISSN:0888-5885
1520-5045
DOI:10.1021/acs.iecr.3c00802