Synthesis of Tetrasubstituted Enamines Using Secondary Amines and In Situ-Generated Allenes from Nitrocyclopropanes

A novel reaction of cyclic and acyclic secondary amines with in situ-generated allene intermediate species from nitro-substituted donor–acceptor cyclopropanes is reported. In the presence of a simple inorganic base, NaOH, tetrasubstituted enamine derivatives can be obtained in moderate to excellent...

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Bibliographic Details
Published in:Journal of organic chemistry 2024-10, Vol.89 (19), p.13868-13875
Main Authors: Xu, Zhong-Yang, Wei, Jian-Sheng, Liu, Li, Hu, Qing-Bo, Zhu, Jin-Yao, Zhou, Zhan-Yu, Xia, Ai-Bao, Xu, Dan-Qian
Format: Article
Language:English
Subjects:
allene
enamines
organic chemistry
species
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