Similarity Laws for the Lines of Ideal Free Energy and Chemical Potential in Supercritical Fluids

We have found the curves on the density–temperature plane, along which the values of free energy and chemical potential correspond to ideal gas quantities. At first, we have applied the van der Waals equation to construct them and to derive their equations. Then we have shown that the same lines for...

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Bibliographic Details
Published in:The journal of physical chemistry. B 2017-09, Vol.121 (37), p.8802-8808
Main Authors: Apfelbaum, E. M, Vorob’ev, V. S
Format: Article
Language:English
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Summary:We have found the curves on the density–temperature plane, along which the values of free energy and chemical potential correspond to ideal gas quantities. At first, we have applied the van der Waals equation to construct them and to derive their equations. Then we have shown that the same lines for real substances (Ar, N2, CH4, SF6, H2, H2O) and for the model Lennard-Jones system constructed on the basis of the measurements data and calculations are well matched with the derived equations. The validity and deviations from the obtained similarity laws are discussed.
ISSN:1520-6106
1520-5207
DOI:10.1021/acs.jpcb.7b07157