Postpolymerization Modification-Induced Chiral Self-Assembly of Substituted Poly(phenylacetylene)s Based on Cis–Transoid to Cis–Cisoid Helical Transition

Herein, we developed a novel postpolymerization modification-induced self-assembly (PPMISA) by subtly combining conformational transition-induced self-assembly with an activated ester-amine reaction. During the reaction, the poly­(phenylacetylene) (PPA) backbone can spontaneously transform from cis–...

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Published in:Macromolecules 2025-02, Vol.58 (3), p.1235-1244
Main Authors: Wang, Sheng, Sun, Xiaoqian, Zeng, Hua, Xie, Siyu, Zhang, Jie, Wan, Xinhua
Format: Article
Language:English
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