Photo-to-Thermal Conversion Harnessing Low-Energy Photons Renders Efficient Solar CO 2 Reduction

• Published in: ACS applied materials & interfaces 2024-07, Vol.16 (28), p.36247-36254
• Main Authors: Guo, Chengqi, Jiang, Enhui, Chen, Qiuli, Li, Wanhe, Chen, Yahui, Jia, Shuhan, Zhou, Yiying, Liu, Zhonghuan, Lin, Xinyu, Huo, Pengwei, Li, Chunxiang, Ng, Yun Hau, Crittenden, John Charles, Zhu, Zhi, Yan, Yan
• Format: Article
• Language: English
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.4c03790

Efficient photocatalytic solar CO reduction presents a challenge because visible-to-near-infrared (NIR) low-energy photons account for over 50% of solar energy. Consequently, they are unable to instigate the high-energy reaction necessary for dissociating C═O bonds in CO . In this study, we present a novel methodology leveraging the often-underutilized photo-to-thermal (PTT) conversion. Our unique two-dimensional (2D) carbon layer-embedded Mo C (Mo C-C ) MXene catalyst in black color showcases superior near-infrared (NIR) light absorption. This enables the efficient utilization of low-energy photons via the PTT conversion mechanism, thereby dramatically enhancing the rate of CO photoreduction. Under concentrated sunlight, the optimal Mo C-C catalyst achieves CO reduction reaction rates of 12000-15000 μmol·g ·h to CO and 1000-3200 μmol·g ·h to CH . Notably, the catalyst delivers solar-to-carbon fuel (STF) conversion efficiencies between 0.0108% to 0.0143% and the STF = 0.0123%, the highest recorded values under natural sunlight conditions. This innovative approach accentuates the exploitation of low-frequency, low-energy photons for the enhancement of photocatalytic CO reduction.