Lab-Scale Alkaline Water Electrolyzer for Bridging Material Fundamentals with Realistic Operation

• Published in: ACS sustainable chemistry & engineering 2018-04, Vol.6 (4), p.4829-4837
• Main Authors: Ju, Wenbo, Heinz, Meike V. F, Pusterla, Lorenzo, Hofer, Matthias, Fumey, Benjamin, Castiglioni, Roberto, Pagani, Marco, Battaglia, Corsin, Vogt, Ulrich F
• Format: Article
• Language: English
• ISSN: 2168-0485; 2168-0485
• DOI: 10.1021/acssuschemeng.7b04173

Hydrogen produced by water electrolysis with renewable electricity is a reliable, affordable and environmental friendly energy carrier for future energy supply and storage. Alkaline water electrolysis is a well matured technique and proved to be suitable for large-scale applications. Materials development for alkaline water electrolyzers is still of interest for academia and industry to address the issues of low compatibility to renewable power sources. A lab-scale system for alkaline water electrolysis was developed, aiming to advance materials development and to bridge the intrinsic properties of materials with their performance under realistic operating conditions. As the smallest pressure-type electrolyzer, it is capable of working at 30 bar and 80 °C with continuous liquid electrolyte circulation. Experimental studies investigate the influence of temperature, pressure, and intrinsic properties of materials on voltage efficiency and hydrogen purity. With appropriate analysis, links between material specifications and overall performance can be established, encouraging new designs and material innovations for alkaline water electrolysis.