Monodispersed InP Quantum Dots Prepared by Colloidal Chemistry in a Noncoordinating Solvent

• Published in: Chemistry of materials 2005-07, Vol.17 (14), p.3754-3762
• Main Authors: Lucey, Derrick W, MacRae, David J, Furis, Madalina, Sahoo, Yudhisthira, Cartwright, Alexander N, Prasad, Paras N
• Format: Article
• Language: English
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/cm050110a

III−V semiconductor quantum dots are of considerable interest as their applications cover a broad spectrum, from optoelectronic to biomedical technology. For them to be of practical value, there is a need for a method that provides rapid and scalable production of highly monodispersed nanoparticles. This paper reports an efficient and rapid method of producing highly monodispersed InP quantum dots using a novel precursor-based colloidal synthesis in a noncoordinating solvent. The method also allows judicious control over the size of the quantum dots and can also be extended to produce other III−V quantum dots. In this paper, the synthesis and characterization of highly monodispersed InP quantum dots from newly prepared indium(III) carboxylate complexes in octadecene are detailed. When using indium(III) carboxylate as the indium precursor, no surfactant or coordinating solvents are required to prepare high-quality InP quantum dots in octadecene. The in situ formation of a surfactant upon injection of the phosphine precursor [P(SiMe3)3] helps control the growth of the resulting quantum dots. Structural and optical studies (continuous wave and time-resolved) have been performed on the as-prepared InP quantum dots. In addition, time-resolved photoluminescence has been conducted on etched InP quantum dots. The effects of the carboxylate chain length in indium(III) carboxylate and injection temperature on the growth and properties of quantum dots have been studied.