Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy

• Published in: Chemistry of materials 2011-12, Vol.23 (24), p.5415-5424
• Main Authors: Croy, Jason R, Balasubramanian, Mahalingam, Kim, Donghan, Kang, Sun-Ho, Thackeray, Michael M
• Format: Article
• Language: English
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/cm2026703

We have taken advantage of the element specific nature of X-ray absorption spectroscopy to elucidate the chemical and structural details of a surface treatment intended for the protection of high-capacity cathode materials. Electrochemical data have shown that surface treatments of 0.5Li2MnO3•0.5LiCoO2 (Li1.2Mn0.4Co0.4O2) with an acidic solution of lithium–nickel-phosphate significantly improves electrode capacity, rate, and cycling stability. XAS data reveal that the surface treatment results in a modification of the composite structure itself, where Ni2+ cations, intended to be present in a lithium–nickel-phosphate coating, have instead displaced lithium in the transition metal layers of Li2MnO3-like domains within the 0.5Li2MnO3•0.5LiCoO2 structure. X-ray diffraction data show the presence of Li3PO4, suggesting that phosphate ions from the acidic solution are responsible for lithium extraction and nickel insertion with the formation of vacancies and/or manganese reduction for charge compensation. Furthermore, we show that the above effects are not limited to lithium–nickel-phosphate treatments. The studies described are consistent with a novel approach for synthesizing and tailoring the structures of high-capacity cathode materials whereby a Li2MnO3 framework is used as a precursor for synthesizing a wide variety of composite metal oxide insertion electrodes for Li-ion battery applications.