Silica Decomposition Using a Transferred Arc Process

• Published in: Industrial & engineering chemistry research 1999-06, Vol.38 (6), p.2299-2309
• Main Authors: Addona, Tony, Munz, Richard J
• Format: Article
• Language: English
• Subjects: Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; Powders
• ISSN: 0888-5885; 1520-5045
• DOI: 10.1021/ie980652k

A novel process for silica decomposition consisting of transferring a thermal arc directly to a silica anode was investigated. The effects of current (150−250 A), plasma gas flow rate (10−20 L/min of Ar), and plasma gas composition (0−2.8% H2) on the rate of decomposition were examined. The decomposition rate ranged from 0.09 to 1.8 g/min and was determined to be heat-transfer-limited, with decomposition occurring below the arc root where the anode surface attained its boiling point. The decomposition rate was independent of plasma gas flow rate, suggesting that convective heat transfer was reduced significantly by the counterflow of decomposition products (SiO(g) and O2) from the surface. Increasing the current increased the decomposition rate because heat input to the anode because of electron flow and arc radiation increased. Adding H2 to the plasma gas increased the decomposition rate because of an increase in radiative heat transfer to the anode, a reduction in the theoretical energy requirement for decomposition, and a consumption of O2 which lowered the silica boiling point. The fumed silica produced had properties typical of commercial fumed silica products.