Rhodium-Catalyzed Carbonylative [3+2+1] Cycloaddition Reaction:  Catalytic Formation of Bicyclic Cyclohexenones from Trienes and Carbon Monoxide

The rhodium-catalyzed carbonylative [3+2+1] cycloaddition of trienes into bicyclohexenones has been developed. The carbonylated cycloaddition products have a high regioselectivity. This catalytic system tolerates functionalities including ether, sulfonamide, and ester.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2004-03, Vol.126 (9), p.2714-2715
Main Authors: Lee, Sang Ick, Park, Ji Hoon, Chung, Young Keun, Lee, Sueg-Geun
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Organic chemistry
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Summary:The rhodium-catalyzed carbonylative [3+2+1] cycloaddition of trienes into bicyclohexenones has been developed. The carbonylated cycloaddition products have a high regioselectivity. This catalytic system tolerates functionalities including ether, sulfonamide, and ester.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja039301+