Effect of Ion Exchange on the Adsorption of Steam Methane Reforming Off-Gases on Zeolite 13X

• Published in: Journal of chemical and engineering data 2010-01, Vol.55 (1), p.184-195
• Main Authors: Lopes, Filipe V. S, Grande, Carlos A, Ribeiro, Ana M, Vilar, Vítor J. P, Loureiro, José M, Rodrigues, Alírio E
• Format: Article
• Language: English
• Subjects: Alternative fuels. Production and utilization; Applied sciences; Chemistry; Energy; Exact sciences and technology; Fuels; General and physical chemistry; Hydrogen; Solid-gas interface; Surface physical chemistry
• ISSN: 0021-9568; 1520-5134
• DOI: 10.1021/je900303y

In this study, we have modified a material with enhanced adsorption capacity and kinetics toward nitrogen to apply in a layered pressure swing adsorption (PSA) unit for separation of steam methane reforming (SMR) off-gases. The adsorption properties of the base zeolite 13X (sodium form) were modified by changing the cation with lithium, barium, and calcium. The best adsorbent was selected by determining the difference in adsorption capacity measured by breakthrough experiments with (0.01 and 0.25) bar of partial pressure of nitrogen (effective capacity in a PSA unit) and the crystal diffusivity [at (303 and 323) K]. The ion exchange of zeolite 13X with Ba2+ and Ca2+ will favor nitrogen adsorption, with the calcium-modified sample having better performance (higher adsorption capacity). Adsorption equilibrium and kinetics of N2, H2, CO, CH4, and CO2 on ion-exchanged zeolite 13X-Ca were studied at (303 and 323) K in the pressure range (0 to 7) bar. At 1 bar of N2, the loading of the 13X-Ca was 0.447 mol·kg−1 against 0.288 mol·kg−1 of the original 13X-Na zeolite.