Molten-salt treatment of waste biomass for preparation of carbon with enhanced capacitive properties and electrocatalytic activity towards oxygen reduction

Carbon powders are building blocks for electrochemical energy storage/conversion devices. Green, cost-affordable and facile preparation of carbon with applicable electrochemical properties is therefore essential for effective utilization of fluctuating renewable energy. Herein, the preparation of ca...

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Bibliographic Details
Published in:Faraday discussions 2016-08, Vol.19, p.147-159
Main Authors: Lu, Beihu, Zhou, Jing, Song, Yuqiao, Wang, Hailong, Xiao, Wei, Wang, Dihua
Format: Article
Language:English
Subjects:
Biomass
Carbon
Microstructure
Nanostructure
Oxygen
Reduction
Surface chemistry
Wastes
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Summary:Carbon powders are building blocks for electrochemical energy storage/conversion devices. Green, cost-affordable and facile preparation of carbon with applicable electrochemical properties is therefore essential for effective utilization of fluctuating renewable energy. Herein, the preparation of carbon nanoflakes via impregnation of waste biomass i.e. boiled coffee beans in molten Na 2 CO 3 -K 2 CO 3 (with equal mass) at 800 °C and molten CaCl 2 at 850 °C is reported. The microstructure and surface chemistry of the obtained carbons are specified. The correlations between synthetic conditions and microstructure/surface chemistry of the obtained carbons are rationalized. The derived carbon nanosheets are tested and compared as active materials for supercapacitors in a configuration of symmetric full cells in 1 M MeEt 3 NBF 4 in acetonitrile and electrocatalysts towards the oxygen reduction reaction (ORR) in O 2 -saturated 0.1 M aqueous KOH. Despite the lower surface area, the carbon nanosheets derived in molten Na 2 CO 3 -K 2 CO 3 exhibit enhanced capacitive properties and electrocatalytic ORR activity. The present study highlights the importance of thermal media on the microstructure, surface chemistry and electrochemistry of carbon from biomass.
ISSN:1359-6640
1364-5498
DOI:10.1039/c5fd00215j