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Metal-free oxidative carbonylation on enaminone CC bond for the cascade synthesis of benzothiazole-containing vicinal diketones
The cascade reactions between enaminones and o -aminothiophenols have been implemented to provide unprecedented vicinal diketones containing benzothiazole structures. The construction of the products has been realized under metal-free conditions via carbonylation on the CC double bond of the enamin...
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Published in: | Green chemistry : an international journal and green chemistry resource : GC 2016, Vol.18 (2), p.402-405 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The cascade reactions between enaminones and
o
-aminothiophenols have been implemented to provide unprecedented vicinal diketones containing benzothiazole structures. The construction of the products has been realized under metal-free conditions
via
carbonylation on the CC double bond of the enaminone. The tunable synthesis of 2-aroylbenzothiazoles has been achieved by using identical starting materials under modified reaction conditions. |
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ISSN: | 1463-9262 1463-9270 |
DOI: | 10.1039/C5GC01821H |