Graphene quantum dot engineered ultrathin loose polyamide nanofilms for high-performance nanofiltration

Pursuing high water permeance with ultrahigh selectivity is a longstanding objective for nanofiltration membranes. At present, simultaneously engineering an ultrathin thickness and loose architecture of nanofiltration membranes is in great demand and a severe challenge. Herein, we demonstrate a two-...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2020-01, Vol.8 (45), p.2393-23938
Main Authors: Li, Yafei, You, Xinda, Li, Ya, Yuan, Jinqiu, Shen, Jianliang, Zhang, Runnan, Wu, Hong, Su, Yanlei, Jiang, Zhongyi
Format: Article
Language:English
Subjects:
Chemical interactions
Diffusion rate
Filtration
Graphene
Membranes
Nanofiltration
Nanotechnology
Piperazine
Polyamide resins
Polyamides
Polymerization
Pore size
Porosity
Quantum dots
Regulators
Reluctance
Selectivity
Sodium sulfate
Thickness
Upper bounds
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Summary:Pursuing high water permeance with ultrahigh selectivity is a longstanding objective for nanofiltration membranes. At present, simultaneously engineering an ultrathin thickness and loose architecture of nanofiltration membranes is in great demand and a severe challenge. Herein, we demonstrate a two-in-one strategy toward ultrathin loose polyamide (ULPA) nanofilms via graphene quantum dot (GQD)-mediated support-free interfacial polymerization. Featuring favorable chemical interactions and size, GQDs serve as quasi-molecule-scale regulators to reduce the diffusion rate of piperazine, and generate ULPA nanofilms with a controllable thickness from 18.3 to 5.5 nm. Concomitantly, GQDs are incorporated into ULPA during interfacial polymerization to construct a loose structure, which is manifested by an enlarged pore size. The resultant ULPA composite membranes overcome the upper-bound limit of polyamide membranes, exhibiting a water permeance of 32.1 L m −2 h −1 bar −1 with an ultrahigh Na 2 SO 4 rejection of 99.6%, as well as an unprecedented Cl − /SO 4 2− selectivity of 205.8 that reaches the highest value ever reported. This two-in-one strategy may open a facile avenue to design advanced membranes for environmental and energy relevant applications. Graphene quantum dot-mediated interfacial polymerization generates ultrathin loose polyamide nanofilms for high-performance nanofiltration.
ISSN:2050-7488
2050-7496
DOI:10.1039/d0ta09319j