Influence of MO-GaN templates on the HVPE growth of semi-polar GaN thick films

• Published in: CrystEngComm 2021-05, Vol.23 (18), p.3364-337
• Main Authors: Zhang, Lin, Wu, Jiejun, Han, Tong, Liu, Fang, Li, Mengda, Zhu, Xingyu, Zhao, Qiyue, Yu, Tongjun
• Format: Article
• Language: English
• Subjects: Free energy; Heat of formation; Metalorganic chemical vapor deposition; Organic chemicals; Organic chemistry; Process parameters; Sapphire; Thick films; Vapor phase epitaxy; Vapor phases
• ISSN: 1466-8033; 1466-8033
• DOI: 10.1039/d1ce00040c

In this paper, the growth of semi-polar GaN thick films was investigated on an m -plane sapphire by hydride vapor phase epitaxy (HVPE). By optimizing parameters of the HVPE process, both (11−22) and (10−13) semi-polar GaN films have been successfully obtained with a mirror surface and excellent crystal quality on different GaN templates grown by metal organic chemical vapor deposition (MOCVD), respectively. The influence of MO-GaN templates on the HVPE growth was further studied. The results revealed that the same plane of a semi-polar HVPE-GaN thick layer was grown on a single-phase template, such as GaN (11−22) HVPE on (11−22) MO-template and GaN (10−13) HVPE on (10−13) MO-template . However, on mixed-phase MO-templates, a single-phase (11−22) GaN thick layer was found to grow even if the original templates contain both (11−22) and (10−13) plane components. Meanwhile, in contrast with the difficult growth of GaN (10−13) with a smooth surface, it is easier to acquire GaN (11−22) thick layers by a HVPE method. A wider window for the growth of the (11−22) plane could partly explain the reason why the pure GaN (11−22) plane could be grown on mixed-phase ((11−22) & (10−13)) MO-templates. In order to explain this phenomenon, both formation energy ( E f ) and migration barrier ( E m ) of these semi-polar faces were calculated. Our results indicated that the E f of GaN (10−13) (−0.56 eV) is higher than that of (11−22) (−10.73 eV), and the E m of (10−13) (0.30 eV) is lower than that of (11−22) (1.89 eV). So the (11−22)-plane growth was more likely to be prevalent in competition between two phases. This work illustrates the influence of MO-templates and competition mechanism on the HVPE growth of semi-polar GaN (11−22) & (10−13) thick layers.