The tetracyanoborate anion as a building block for the heterocubane cluster cage [Cr 4 B(CN) 4 4 ] 4

The tetracyanoborate anion [B(CN) 4 ] − (TCB) was utilized as a building block for the synthesis of polynuclear chromium carbonyl compounds upon photolytic reaction with [Cr(CO) 6 ]. Up to four κN-coordinated cyano groups of TCB can be involved in binding to chromium, giving mixtures of [B(CN) 4− x...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-08, Vol.60 (65), p.8621-8624
Main Authors: Luff, Martin S., Bertermann, Rüdiger, Finze, Maik, Radius, Udo
Format: Article
Language:English
Subjects:
Anions
Cages
Carbonyl compounds
Carbonyls
Chemical synthesis
Chromium
Cyano groups
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