Synthesis of organo-uranium() species in the gas-phase using reactions between [UH] and nitriles

One challenge in the quest to map the intrinsic reactivity of model actinide species has been the controlled synthesis of organo-actinide ions in the gas phase. We report here evidence that a series of gas-phase, σ-bonded [U-R] + species (where R = CH 3 , C 2 H 3 , C 2 H 5 , C 3 H 7 , or C 5 H 6 ) c...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2024-12, Vol.54 (1), p.231-238
Main Authors: Terhorst, Justin G, Corcovilos, Theodore A, Lenze, Samuel J, van Stipdonk, Michael J
Format: Article
Language:English
Subjects:
Cascade chemical reactions
Chemical synthesis
Density functional theory
Mass spectrometry
Nitriles
Vapor phases
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