Diastereoselective Gold(I)-Catalyzed [2+2+2] Cycloaddition of Oxo-1,5-enynes

Abstract The intramolecular gold(I)-catalyzed [2+2+2] cycloaddition of oxo-1,5-enynes bearing protected homopropargylic alcohols provides access to oxatricyclic adducts with good to excellent diastereoselectivity.

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Bibliographic Details
Published in:Synthesis (Stuttgart) 2016-10, Vol.48 (19), p.3183-3198
Main Authors: Calleja, Pilar, Muratore, Michael E., Jiménez, Tania, Echavarren, Antonio M.
Format: Article
Language:English
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Description
Summary:Abstract The intramolecular gold(I)-catalyzed [2+2+2] cycloaddition of oxo-1,5-enynes bearing protected homopropargylic alcohols provides access to oxatricyclic adducts with good to excellent diastereoselectivity.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0035-1562452