Non-Markovian effects on quantum optimal control of dissipative wave packet dynamics

• Published in: The Journal of chemical physics 2003-07, Vol.119 (2), p.661-671
• Main Author: Ohtsuki, Yukiyoshi
• Format: Article
• Language: English
• ISSN: 0021-9606; 1089-7690
• DOI: 10.1063/1.1576385

Optimal control within the density matrix formalism is applied to the creation of a specified superposition state in condensed phases. The primary system modeled by a displaced harmonic oscillator is surrounded by a boson heat bath, the dynamics of which is described by a non-Markovian master equation. A newly developed monotonically convergent algorithm is used to solve the pulse design equations. The control mechanisms are strongly dependent on the bath correlation time that is characterized by the inverse of an exponential decay constant, γ. If the correlation time is shorter than the temporal width of a typical subpulse involved in an optimal pulse, the solution is reduced to that in the Markovian case. If we assume a longer correlation time, by weighing less physical significance on the penalty due to pulse fluence, an optimal pulse with high intensity is obtained, the temporal width of which approaches ∼1/γ. We also see considerable changes in the shape of the optimal pulse with increasing intensity, suggesting that strong fields open up control mechanisms that are qualitatively different from those in weak fields.