Structure and magnetotransport properties of epitaxial nanocomposite La0.67Ca0.33MnO3:SrTiO3 thin films grown by a chemical solution approach

• Published in: Applied physics letters 2012-02, Vol.100 (8)
• Main Authors: Fei, Ling, Zhu, Leyi, Cheng, Xuemei, Wang, Haiyan, Baber, Stacy M., Hill, Joshua, Lin, Qianglu, Xu, Yun, Deng, Shuguang, Luo, Hongmei
• Format: Article
• Language: English
• ISSN: 0003-6951; 1077-3118
• DOI: 10.1063/1.3688048

Epitaxial La0.67Ca0.33MnO3:SrTiO3 (LCMO:STO) composite thin films have been grown on single crystal LaAlO3(001) substrates by a cost effective polymer-assisted deposition method. Both x-ray diffraction and high-resolution transmission electron microscopy confirm the growth of epitaxial films with an epitaxial relationship between the films and the substrates as (002)film||(002)sub and [202]film||[202]sub. The transport property measurement shows that the STO phase significantly increases the resistivity and enhances the magnetoresistance (MR) effect of LCMO and moves the metal-insulator transition to lower temperatures. For example, the MR values measured at magnetic fields of 0 and 3 T are −44.6% at 255 K for LCMO, −94.2% at 125 K for LCMO:3% STO, and −99.4% at 100 K for LCMO:5% STO, respectively.