Selectivity of the Lewis acid-induced transformations of polyfunctional compounds containing a 4,6-dialkoxy-7-(arylthio)heptene moiety

The interaction of the title adducts with Lewis acids may proceed as an attack at either β-alkoxy or δ-alkoxy group to the arylthio substituent leading to the formation of substituted cyclohexane or 1,3-diene derivatives, respectively.

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Bibliographic Details
Published in:Mendeleev communications 2001, Vol.11 (5), p.176-178
Main Authors: Chekmarev, Dmitrii S., Maskaev, Andrei V., Zatonsky, Georgy V., Lazareva, Margarita I., Caple, Ron, Smit, William A.
Format: Article
Language:English
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Description
Summary:The interaction of the title adducts with Lewis acids may proceed as an attack at either β-alkoxy or δ-alkoxy group to the arylthio substituent leading to the formation of substituted cyclohexane or 1,3-diene derivatives, respectively.
ISSN:0959-9436
DOI:10.1070/MC2001v011n05ABEH001513