Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation

The radical anion of di(2,6-diethylphenyl)stannylene (Ar 2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar 2Sn) 3, and the electrochemical oxidation of cyclo-(Ar 2Sn) 3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.

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Bibliographic Details
Published in:Mendeleev communications 2002, Vol.12 (4), p.125-126
Main Authors: Orlov, Ivan S., Moiseeva, Anna A., Butin, Kim P., Sita, Lawrence R., Egorov, Mikhail P., Nefedov, Oleg M.
Format: Article
Language:English
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Summary:The radical anion of di(2,6-diethylphenyl)stannylene (Ar 2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar 2Sn) 3, and the electrochemical oxidation of cyclo-(Ar 2Sn) 3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.
ISSN:0959-9436
DOI:10.1070/MC2002v012n04ABEH001601