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Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation
The radical anion of di(2,6-diethylphenyl)stannylene (Ar 2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar 2Sn) 3, and the electrochemical oxidation of cyclo-(Ar 2Sn) 3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.
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Published in: | Mendeleev communications 2002, Vol.12 (4), p.125-126 |
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container_end_page | 126 |
container_issue | 4 |
container_start_page | 125 |
container_title | Mendeleev communications |
container_volume | 12 |
creator | Orlov, Ivan S. Moiseeva, Anna A. Butin, Kim P. Sita, Lawrence R. Egorov, Mikhail P. Nefedov, Oleg M. |
description | The radical anion of di(2,6-diethylphenyl)stannylene (Ar
2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar
2Sn)
3, and the electrochemical oxidation of cyclo-(Ar
2Sn)
3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane. |
doi_str_mv | 10.1070/MC2002v012n04ABEH001601 |
format | article |
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2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar
2Sn)
3, and the electrochemical oxidation of cyclo-(Ar
2Sn)
3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.</abstract><pub>Elsevier B.V</pub><doi>10.1070/MC2002v012n04ABEH001601</doi><tpages>2</tpages></addata></record> |
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title | Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation |
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