Optical antenna enhanced spontaneous emission

• Published in: Proceedings of the National Academy of Sciences - PNAS 2015-02, Vol.112 (6), p.1704-1709
• Main Authors: Eggleston, Michael S., Messer, Kevin, Zhang, Liming, Yablonovitch, Eli, Wu, Ming C.
• Format: Article
• Language: English
• Subjects: Antennas; ATOMIC AND MOLECULAR PHYSICS; Atoms & subatomic particles; Frequencies; metal optics; Molecules; nanophotonics; NANOSCIENCE AND NANOTECHNOLOGY; Nanostructured materials; Physical Sciences; plasmonics; Quantum physics; ultrafast devices
• ISSN: 0027-8424; 1091-6490
• DOI: 10.1073/pnas.1423294112

Significance Since the invention of the laser over 50 y ago, stimulated emission has been stronger and far more important than spontaneous emission, the ordinary light we are accustomed to. Indeed spontaneous emission has been looked down upon as a weak effect. Now a new science of enhanced spontaneous emission is emerging that makes spontaneous emission faster than stimulated emission. This new science depends upon the use of optical antennas to increase the spontaneous emission rate. Antennas emerged at the dawn of radio for concentrating electromagnetic energy to a small volume. Despite the importance of radio antennas, 100 y went by before optical antennas began to be used to help extract optical frequency radiation from very small sources such as dye molecules and quantum dots. Atoms and molecules are too small to act as efficient antennas for their own emission wavelengths. By providing an external optical antenna, the balance can be shifted; spontaneous emission could become faster than stimulated emission, which is handicapped by practically achievable pump intensities. In our experiments, InGaAsP nanorods emitting at ∼200 THz optical frequency show a spontaneous emission intensity enhancement of 35× corresponding to a spontaneous emission rate speedup ∼115×, for antenna gap spacing, d = 40 nm. Classical antenna theory predicts ∼2,500× spontaneous emission speedup at d ∼ 10 nm, proportional to 1/ d ². Unfortunately, at d < 10 nm, antenna efficiency drops below 50%, owing to optical spreading resistance, exacerbated by the anomalous skin effect (electron surface collisions). Quantum dipole oscillations in the emitter excited state produce an optical ac equivalent circuit current, I ₒ = qω | x ₒ|/ d , feeding the antenna-enhanced spontaneous emission, where q | x ₒ| is the dipole matrix element. Despite the quantum-mechanical origin of the drive current, antenna theory makes no reference to the Purcell effect nor to local density of states models. Moreover, plasmonic effects are minor at 200 THz, producing only a small shift of antenna resonance frequency.