Unexpected Reaction Of A-Aryl-N-(P-Phenylethyl) Nitrones With Chlorinating Agents

The a-aryl-N-(β-phenylethyl)nitrones when subjected to SO 2 Cl 2 /Et 3 N and NCS/NaOMe treatment independently, gave unexpectedly the corresponding amides. These procedures form an alternative route for the rearrangement of nitrones to amides.

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Bibliographic Details
Published in:Synthetic communications 1999-06, Vol.29 (11), p.2013-2017
Main Authors: Mohan, Ponnusamy, Vanangamudi, Arumugasamy, Thirumalaikumar, Muniappan, Muthusubramanian, Shanmugam, Sivasubramanian, Shunmugaperumal
Format: Article
Language:English
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Summary:The a-aryl-N-(β-phenylethyl)nitrones when subjected to SO 2 Cl 2 /Et 3 N and NCS/NaOMe treatment independently, gave unexpectedly the corresponding amides. These procedures form an alternative route for the rearrangement of nitrones to amides.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919908086190