Phosphorylation of Conjugated Enamines

Introduction of benzylidene group at α-position of enamines derived from cyclic ketones substantially increases strength of C-P bond thus permitting further syntheses without splitting of the C-P bond. A wide set of phosphorylated derivatives of type (I) were prepared and their properties were studi...

Full description

Saved in:
Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1999-01, Vol.147 (1), p.485-485
Main Authors: Kostyuk, Aleksandr N., Lysenko, Nikolai V., Dovgopoly, Sergei I., Tolmachev, Andrei A.
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Introduction of benzylidene group at α-position of enamines derived from cyclic ketones substantially increases strength of C-P bond thus permitting further syntheses without splitting of the C-P bond. A wide set of phosphorylated derivatives of type (I) were prepared and their properties were studied. Combination of an enamine moiety with other nucleophilic centers such as C or N in a molecule allows to carry out cyclisation giving five- and six-membered phosphorus-containing heterocycles of types (II, III).
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509908053722