Cycloaddition Reaction of Epoxides with Various Alkenes Under Microwave Irradiation

The reactivity of gem-dicyano epoxides with various alkenes is studies in solvent free conditions, and in homogeneous solution, under microwave irradiation. Microwave heating of these substrates in solvent, yields carbonyl ylides which give 1-3-dipolar cycloaddition.

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Bibliographic Details
Published in:Synthetic communications 2003-06, Vol.33 (11), p.1861-1866
Main Authors: Bentabed, Ghania, Derdour, Aicha, Benhaoua, Hadj
Format: Article
Language:English
Subjects:
1,3-Dipolar cycloaddition
Epoxides
Microwave irradiation
Tetrahydrofuran derivatives
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Description
Summary:The reactivity of gem-dicyano epoxides with various alkenes is studies in solvent free conditions, and in homogeneous solution, under microwave irradiation. Microwave heating of these substrates in solvent, yields carbonyl ylides which give 1-3-dipolar cycloaddition.
ISSN:0039-7911
1532-2432
DOI:10.1081/SCC-120020196