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Crystal structure of the copper(I) complex Cu(py-Clan)(PPh3)I
A mixed ligand copper(I) Schiff base complex [Cu(py-Clan)(PPh 3 )I], where py-Clan = = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral ge...
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| Published in: | Journal of structural chemistry 2015, Vol.56 (1), p.175-178 |
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| Main Authors: | , , , |
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| Language: | English |
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| container_end_page | 178 |
| container_issue | 1 |
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| container_title | Journal of structural chemistry |
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| creator | Khalaji, A. D. Jafari, K. Fejfarova, K. Dusek, M. |
| description | A mixed ligand copper(I) Schiff base complex [Cu(py-Clan)(PPh
3
)I], where py-Clan = = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral geometry. The Schiff base py-Clan ligand acts as a chelating ligand and coordinates to the copper center via two nitrogen atoms. The [Cu(py-Clan)(PPh
3
)I] complex crystallizes in the monoclinic space group
P
2
1
/
c
with unit cell parameters:
a
= 10.3339(12) Å,
b
= 34.524 Å,
c
= 8.3940 Å, β = 114.759(8)°,
V
= 2719.4(5) Å
3
and
Z
= 4. |
| doi_str_mv | 10.1134/S0022476615010230 |
| format | article |
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3
)I], where py-Clan = = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral geometry. The Schiff base py-Clan ligand acts as a chelating ligand and coordinates to the copper center via two nitrogen atoms. The [Cu(py-Clan)(PPh
3
)I] complex crystallizes in the monoclinic space group
P
2
1
/
c
with unit cell parameters:
a
= 10.3339(12) Å,
b
= 34.524 Å,
c
= 8.3940 Å, β = 114.759(8)°,
V
= 2719.4(5) Å
3
and
Z
= 4.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476615010230</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Brief Communications ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2015, Vol.56 (1), p.175-178</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c240t-5e2ce12ff7c8d33d78a5a4b1f4ffc40e99e3d2e9e1e61bef60b148885a57b2443</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Khalaji, A. D.</creatorcontrib><creatorcontrib>Jafari, K.</creatorcontrib><creatorcontrib>Fejfarova, K.</creatorcontrib><creatorcontrib>Dusek, M.</creatorcontrib><title>Crystal structure of the copper(I) complex Cu(py-Clan)(PPh3)I</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>A mixed ligand copper(I) Schiff base complex [Cu(py-Clan)(PPh
3
)I], where py-Clan = = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral geometry. The Schiff base py-Clan ligand acts as a chelating ligand and coordinates to the copper center via two nitrogen atoms. The [Cu(py-Clan)(PPh
3
)I] complex crystallizes in the monoclinic space group
P
2
1
/
c
with unit cell parameters:
a
= 10.3339(12) Å,
b
= 34.524 Å,
c
= 8.3940 Å, β = 114.759(8)°,
V
= 2719.4(5) Å
3
and
Z
= 4.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Brief Communications</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9j0FLw0AQhRdRsFZ_gLcc00N0ZneT3Rw8SLBaKFhQz2GzmbWWNAm7Cdh_b0q9CZ7ewHvf8B5jtwh3iELevwFwLlWWYQoIXMAZm2GqRKKVys_Z7GgnR_-SXYWwA4Bc59mMPRT-EAbTRGHwox1GT1HnomFLke36nny8WkzXvm_oOyrGuD8kRWPaRbzZbMVidc0unGkC3fzqnH0sn96Ll2T9-rwqHteJ5RKGJCVuCblzyupaiFppkxpZoZPOWQmU5yRqTjkhZViRy6BCqbVOTaoqLqWYMzz9tb4LwZMre_-1N_5QIpTH_eWf_RPDT0yYsu0n-XLXjb6dav4D_QDd9lr8</recordid><startdate>2015</startdate><enddate>2015</enddate><creator>Khalaji, A. D.</creator><creator>Jafari, K.</creator><creator>Fejfarova, K.</creator><creator>Dusek, M.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2015</creationdate><title>Crystal structure of the copper(I) complex Cu(py-Clan)(PPh3)I</title><author>Khalaji, A. D. ; Jafari, K. ; Fejfarova, K. ; Dusek, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-5e2ce12ff7c8d33d78a5a4b1f4ffc40e99e3d2e9e1e61bef60b148885a57b2443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Brief Communications</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khalaji, A. D.</creatorcontrib><creatorcontrib>Jafari, K.</creatorcontrib><creatorcontrib>Fejfarova, K.</creatorcontrib><creatorcontrib>Dusek, M.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khalaji, A. D.</au><au>Jafari, K.</au><au>Fejfarova, K.</au><au>Dusek, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of the copper(I) complex Cu(py-Clan)(PPh3)I</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2015</date><risdate>2015</risdate><volume>56</volume><issue>1</issue><spage>175</spage><epage>178</epage><pages>175-178</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>A mixed ligand copper(I) Schiff base complex [Cu(py-Clan)(PPh
3
)I], where py-Clan = = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral geometry. The Schiff base py-Clan ligand acts as a chelating ligand and coordinates to the copper center via two nitrogen atoms. The [Cu(py-Clan)(PPh
3
)I] complex crystallizes in the monoclinic space group
P
2
1
/
c
with unit cell parameters:
a
= 10.3339(12) Å,
b
= 34.524 Å,
c
= 8.3940 Å, β = 114.759(8)°,
V
= 2719.4(5) Å
3
and
Z
= 4.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476615010230</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2015, Vol.56 (1), p.175-178 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S0022476615010230 |
| source | Springer Nature |
| subjects | Atomic Atomic/Molecular Structure and Spectra Brief Communications Chemistry Chemistry and Materials Science Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics |
| title | Crystal structure of the copper(I) complex Cu(py-Clan)(PPh3)I |
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