Partial molar volumes and viscosities of aqueous hippuric acid solutions containing LiCl and MnCl2 · 4H2O at 303.15 K

Density (ρ) and viscosity (η) of aqueous hippuric acid (HA) solutions containing LiCl and MnCl 2 · 4H 2 O have been studied at 303.15 K in order to understand volumetric and viscometric behavior of these systems. Apparent molar volume (φ v ) of salts were calculated from density data and fitted to M...

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Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2015-09, Vol.89 (9), p.1556-1559
Main Authors: Deosarkar, S. D., Tawde, P. D., Zinjade, A. B., Shaikh, A. I.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Physical Chemistry
Physical Chemistry of Solutions
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Summary:Density (ρ) and viscosity (η) of aqueous hippuric acid (HA) solutions containing LiCl and MnCl 2 · 4H 2 O have been studied at 303.15 K in order to understand volumetric and viscometric behavior of these systems. Apparent molar volume (φ v ) of salts were calculated from density data and fitted to Massons relation and partial molar volumes (φ v 0 ) at infinite dilution were determined. Relative viscosity data has been used to determine viscosity A and B coefficients using Jones-Dole relation. Partial molar volume and viscosity coefficients have been discussed in terms of ion-solvent interactions and overall structural fittings in solution.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024415090083