Association of sodium dodecyl sulfate in aqueous solutions according to chemical shifts in 1H NMR spectra

Proton chemical shifts of different atomic groups in sodium dodecyl sulfate (SDS) have been studied by 1 H NMR spectroscopy as functions of surfactant concentration in aqueous solutions. Three surfactant concentration ranges of the chemical shifts have been revealed. The first range corresponds to t...

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Bibliographic Details
Published in:Colloid journal of the Russian Academy of Sciences 2013-09, Vol.75 (5), p.532-537
Main Authors: Idiyatullin, B. Z., Potarikina, K. S., Zuev, Yu. F., Zueva, O. S., Us’yarov, O. G.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Polymer Sciences
Surfaces and Interfaces
Thin Films
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Summary:Proton chemical shifts of different atomic groups in sodium dodecyl sulfate (SDS) have been studied by 1 H NMR spectroscopy as functions of surfactant concentration in aqueous solutions. Three surfactant concentration ranges of the chemical shifts have been revealed. The first range corresponds to the premicellar solutions, the second one is in the vicinity of critical micelle concentration (CMC 1 ), and the third range corresponds to high surfactant concentrations, at which intermicellar interactions play a significant role. The parameters of SDS association (CMC 1 and CMC 2 ) determined based on the concentration dependences of the chemical shifts are in satisfactory agreement with the data available from the literature. The concept of critical dimerization concentration (CDC) has been introduced for the first concentration range. The values of CDC and dimerization constant K 2 (210 × 60 dm 3 /mol) have been estimated within the framework of the two-state model.
ISSN:1061-933X
1608-3067
DOI:10.1134/S1061933X13050037