Thermodynamic characteristics of formation reactions of the vanadium(V) malonate complex

The coordination equilibria in the vanadium(V)-malonic acid system were studied by calorimetry. The heats of formation reactions of the complex VO 2 CH 2 (COO) 2 − at 298.15 K and I = 0.50, 0.75, and 1.00 (NaC1O 4 ) were determined. The standard thermodynamic characteristics of the studied equilibri...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2009-07, Vol.35 (7), p.479-481
Main Authors: Romodanovskii, P. A., Vorob’ev, P. N., Dmitrieva, N. G., Gridchin, S. N., Orlova, T. D.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
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Summary:The coordination equilibria in the vanadium(V)-malonic acid system were studied by calorimetry. The heats of formation reactions of the complex VO 2 CH 2 (COO) 2 − at 298.15 K and I = 0.50, 0.75, and 1.00 (NaC1O 4 ) were determined. The standard thermodynamic characteristics of the studied equilibria were calculated.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328409070021