Oxidation of magnesium with carbon tetrachloride in aprotic solvents

Formal kinetic regularities and the end products of oxidation of magnesium with carbon tetrachloride in the environment of dipolar aprotic solvents were revealed. The effective equilibrium constant, enthalpy and entropy of adsorption of carbon tetrachloride and N,N -dimethylformamide at a metal surf...

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Bibliographic Details
Published in:Russian journal of general chemistry 2011-09, Vol.81 (9), p.1834-1838
Main Authors: Panteleev, S. V., Spirina, I. V., Maslennikov, S. V., Mishchenko, O. G.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Summary:Formal kinetic regularities and the end products of oxidation of magnesium with carbon tetrachloride in the environment of dipolar aprotic solvents were revealed. The effective equilibrium constant, enthalpy and entropy of adsorption of carbon tetrachloride and N,N -dimethylformamide at a metal surface, the rate constant and activation energy of the investigated reaction were determined. The effect of temperature on the dependence of the process on the donor properties of the used coordinating solvents was established and justified. A probable scheme of the process was suggested.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363211090167