Synthesis of 1-(4-isopropenylphenoxy)-bromo-C2-C4-alkanes and application of their transformation products

Reaction of 4-isopropenylphenol with α,ω-dibromo-C 2 -C 4 -alkanes by the Willamson reaction in the presence of potassium iodide as promoter, aiming to synthesize the corresponding monobromosubstituted derivatives and to study their some chemical transformation. Optimal conditions to obtain 1-(4-iso...

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Bibliographic Details
Published in:Russian journal of applied chemistry 2009-10, Vol.82 (10), p.1871-1876
Main Authors: Magerramov, A. M., Bairamov, M. R., Aliev, I. A., Agaeva, M. A., Allakhverdieva, M. G., Mamedov, I. G., Dzhavadov, M. A.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Organic Synthesis and Industrial Organic Chemistry
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Summary:Reaction of 4-isopropenylphenol with α,ω-dibromo-C 2 -C 4 -alkanes by the Willamson reaction in the presence of potassium iodide as promoter, aiming to synthesize the corresponding monobromosubstituted derivatives and to study their some chemical transformation. Optimal conditions to obtain 1-(4-isopropenylphenoxy)-2-bromoethane, 1-(4-isopropenylphenoxy)-3-bromopropane and 1-(4-isopropenylphenoxy)-4-bromobutane were found. The nitrogen-containing derivatives, inhibitors of a hydrosulfuric corrosion in the water-salt solutions, were obtained on the basis of the first two compounds. The derivatives involving multiple bond and ester-group were synthesized from the third compound. Their incorporation into the polystyrene chains in the process synthesis gives them plasticize properties.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427209100243