Reactive Sputtered Ir 1−y Ni y O x Electrocatalysts For The Oxygen Evolution Reaction in Alkaline Media

• Published in: Journal of the Electrochemical Society 2022-07, Vol.169 (7), p.76501
• Main Authors: Coertzen, D., Levecque, P. B. J., Jones, D. R., Dunnill, C. W., Kriek, R. J., Falch, A.
• Format: Article
• Language: English
• ISSN: 0013-4651; 1945-7111
• DOI: 10.1149/1945-7111/ac7adc

One drawback of alkaline water electrolysis (AWE) is the sluggish oxygen evolution reaction (OER) kinetics at the anode of the electrolyser and improvement of the anode material is still a necessity. Various Ir 1−y Ni y O x electrocatalyst combinations were prepared by reactive sputtering and subjected to high-throughput electrochemical screening using a Au/SiO 2 wafer. The best performing electrocatalysts were identified and subjected to single electrode electrochemical and physical characterisation using glassy carbon disk electrodes as the substrate. Rotating disk electrode (RDE) analysis included linear sweep voltammetry (LSV) before and after short term chronopotentiometry (CP). Energy dispersive X-ray spectroscopy and X-ray photo-electron spectroscopy (XPS) confirmed the controlled synthesis of thin film electrocatalysts by utilising reactive sputtering, and confirmed Ir dissolution which occurred during CP measurements. Overall, the Ir 1−y Ni y O x electrocatalyst combinations containing higher amounts of Ir (Ir 92 Ni 8 O x , Ir 68 Ni 32 O x and Ir 62 Ni 38 O x ) performed the best of the evaluated mixed metal oxide electrocatalysts. However, evident from this study was that excellent mass-specific activity (current per mass of noble metal) was not exhibited by the mixed metal oxides when compared to Ni.