Review-Lithium-Excess Layered Cathodes for Lithium Rechargeable Batteries

The exceptionally high gravimetric capacity of lithium-excess layered cathodes (LLCs) has generated interest in their use in lithium-ion batteries (LIBs) for high-capacity applications. Their unique electrochemical and structural properties are responsible for this high capacity, which exceeds the t...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the Electrochemical Society 2015-01, Vol.162 (14), p.A2447-A2467
Main Authors: Hong, Jihyun, Gwon, Hyeokjo, Jung, Sung-Kyun, Ku, Kyojin, Kang, Kisuk
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The exceptionally high gravimetric capacity of lithium-excess layered cathodes (LLCs) has generated interest in their use in lithium-ion batteries (LIBs) for high-capacity applications. Their unique electrochemical and structural properties are responsible for this high capacity, which exceeds the theoretical redox capability of transition metal oxides and have been intensively investigated. However, various fundamental and practical challenges must be overcome before LLCs can be successfully commercialized. The structure of pristine LLCs, which varies with the composition and type of transition metal species used, remains unclear. In addition, the structure continuously changes during electrochemical cycling, which further complicates its understanding. In this review, we discuss the current understanding of LLCs, including their pristine structures, redox chemistries, and structural evolution during cycling, and suggest future research directions to address the critical issues.
ISSN:0013-4651
1945-7111
DOI:10.1149/2.0071514jes