Synthesis of 2-deoxygalactopyranoside derivatives of benzyl alcohols with β-galactosidase from Aspergillus oryzae

Abstract The stereoselective synthesis of 2-deoxyglycosides is a challenge. Glycosidases are capable of catalyzing the synthesis of glycosidic linkages by the absolute stereoselectivity of the anomeric center. We report on an efficient stereoselective synthesis of benzyl β-D-2-deoxygalactopyranoside...

Full description

Saved in:
Bibliographic Details
Published in:Biocatalysis and biotransformation 2014-12, Vol.32 (5-6), p.290-294
Main Authors: Hahn, Przemys aw, Kasprzycka, Anna, Szeja, Wies aw
Format: Article
Language:English
Subjects:
2-deoxygalactosyl derivatives
Aspergillus oryzae
enzymatic synthesis
β-galactosidase
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c395t-fba8e868ae0a7d0c5eee92ec8be6b6c32a5ac4b5c260b6dd4b0cb67eeb754c023
cites cdi_FETCH-LOGICAL-c395t-fba8e868ae0a7d0c5eee92ec8be6b6c32a5ac4b5c260b6dd4b0cb67eeb754c023
container_end_page 294
container_issue 5-6
container_start_page 290
container_title Biocatalysis and biotransformation
container_volume 32
creator Hahn, Przemys aw
Kasprzycka, Anna
Szeja, Wies aw
description Abstract The stereoselective synthesis of 2-deoxyglycosides is a challenge. Glycosidases are capable of catalyzing the synthesis of glycosidic linkages by the absolute stereoselectivity of the anomeric center. We report on an efficient stereoselective synthesis of benzyl β-D-2-deoxygalactopyranosides in the reaction of galactal with alcohols catalyzed using β-galactosidase from Aspergillus oryzae.
doi_str_mv 10.3109/10242422.2014.975216
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_3109_10242422_2014_975216</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1727674163</sourcerecordid><originalsourceid>FETCH-LOGICAL-c395t-fba8e868ae0a7d0c5eee92ec8be6b6c32a5ac4b5c260b6dd4b0cb67eeb754c023</originalsourceid><addsrcrecordid>eNp9kE1OwzAQRiMEElC4AYss2aTYjuMkGxBC_EmVWABra-xMGiMnLnYKpMfiIJyJtIUFGzQLj6zvfRq9KDqhZJpSUp5Rwvg4bMoI5dMyzxgVO9HB-F0mjHOxu9l5ss7sR4chvBBCU1bmB5F_HLq-wWBC7OqYJRW6j2EOFnTvFoOHzgVTYVyhN2_Qmzfc5BR2q8HGYLVrnA3xu-mb-Osz-QFHBALGtXdtfBkW6OfG2uVI-mEFeBTt1WADHv-8k-j55vrp6i6ZPdzeX13OEp2WWZ_UCgosRAFIIK-IzhCxZKgLhUIJnTLIQHOVaSaIElXFFdFK5Igqz7gmLJ1Ep9vehXevSwy9bE3QaC106JZB0pzlIudUpGOUb6PauxA81nLhTQt-kJTItWL5q1iuFcut4hG72GKmq51v4d15W8keBut8PbrTJqzpfxvO_zQ0CLZvNHiUL27pu9HP_yd8AwGZmvI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1727674163</pqid></control><display><type>article</type><title>Synthesis of 2-deoxygalactopyranoside derivatives of benzyl alcohols with β-galactosidase from Aspergillus oryzae</title><source>Taylor and Francis:Jisc Collections:Taylor and Francis Read and Publish Agreement 2024-2025:Science and Technology Collection (Reading list)</source><creator>Hahn, Przemys aw ; Kasprzycka, Anna ; Szeja, Wies aw</creator><creatorcontrib>Hahn, Przemys aw ; Kasprzycka, Anna ; Szeja, Wies aw</creatorcontrib><description>Abstract The stereoselective synthesis of 2-deoxyglycosides is a challenge. Glycosidases are capable of catalyzing the synthesis of glycosidic linkages by the absolute stereoselectivity of the anomeric center. We report on an efficient stereoselective synthesis of benzyl β-D-2-deoxygalactopyranosides in the reaction of galactal with alcohols catalyzed using β-galactosidase from Aspergillus oryzae.</description><identifier>ISSN: 1024-2422</identifier><identifier>EISSN: 1029-2446</identifier><identifier>DOI: 10.3109/10242422.2014.975216</identifier><language>eng</language><publisher>Informa Healthcare</publisher><subject>2-deoxygalactosyl derivatives ; Aspergillus oryzae ; enzymatic synthesis ; β-galactosidase</subject><ispartof>Biocatalysis and biotransformation, 2014-12, Vol.32 (5-6), p.290-294</ispartof><rights>2014 Informa UK, Ltd. 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c395t-fba8e868ae0a7d0c5eee92ec8be6b6c32a5ac4b5c260b6dd4b0cb67eeb754c023</citedby><cites>FETCH-LOGICAL-c395t-fba8e868ae0a7d0c5eee92ec8be6b6c32a5ac4b5c260b6dd4b0cb67eeb754c023</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Hahn, Przemys aw</creatorcontrib><creatorcontrib>Kasprzycka, Anna</creatorcontrib><creatorcontrib>Szeja, Wies aw</creatorcontrib><title>Synthesis of 2-deoxygalactopyranoside derivatives of benzyl alcohols with β-galactosidase from Aspergillus oryzae</title><title>Biocatalysis and biotransformation</title><description>Abstract The stereoselective synthesis of 2-deoxyglycosides is a challenge. Glycosidases are capable of catalyzing the synthesis of glycosidic linkages by the absolute stereoselectivity of the anomeric center. We report on an efficient stereoselective synthesis of benzyl β-D-2-deoxygalactopyranosides in the reaction of galactal with alcohols catalyzed using β-galactosidase from Aspergillus oryzae.</description><subject>2-deoxygalactosyl derivatives</subject><subject>Aspergillus oryzae</subject><subject>enzymatic synthesis</subject><subject>β-galactosidase</subject><issn>1024-2422</issn><issn>1029-2446</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kE1OwzAQRiMEElC4AYss2aTYjuMkGxBC_EmVWABra-xMGiMnLnYKpMfiIJyJtIUFGzQLj6zvfRq9KDqhZJpSUp5Rwvg4bMoI5dMyzxgVO9HB-F0mjHOxu9l5ss7sR4chvBBCU1bmB5F_HLq-wWBC7OqYJRW6j2EOFnTvFoOHzgVTYVyhN2_Qmzfc5BR2q8HGYLVrnA3xu-mb-Osz-QFHBALGtXdtfBkW6OfG2uVI-mEFeBTt1WADHv-8k-j55vrp6i6ZPdzeX13OEp2WWZ_UCgosRAFIIK-IzhCxZKgLhUIJnTLIQHOVaSaIElXFFdFK5Igqz7gmLJ1Ep9vehXevSwy9bE3QaC106JZB0pzlIudUpGOUb6PauxA81nLhTQt-kJTItWL5q1iuFcut4hG72GKmq51v4d15W8keBut8PbrTJqzpfxvO_zQ0CLZvNHiUL27pu9HP_yd8AwGZmvI</recordid><startdate>20141201</startdate><enddate>20141201</enddate><creator>Hahn, Przemys aw</creator><creator>Kasprzycka, Anna</creator><creator>Szeja, Wies aw</creator><general>Informa Healthcare</general><general>Taylor &amp; Francis</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>M7N</scope><scope>P64</scope></search><sort><creationdate>20141201</creationdate><title>Synthesis of 2-deoxygalactopyranoside derivatives of benzyl alcohols with β-galactosidase from Aspergillus oryzae</title><author>Hahn, Przemys aw ; Kasprzycka, Anna ; Szeja, Wies aw</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c395t-fba8e868ae0a7d0c5eee92ec8be6b6c32a5ac4b5c260b6dd4b0cb67eeb754c023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>2-deoxygalactosyl derivatives</topic><topic>Aspergillus oryzae</topic><topic>enzymatic synthesis</topic><topic>β-galactosidase</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hahn, Przemys aw</creatorcontrib><creatorcontrib>Kasprzycka, Anna</creatorcontrib><creatorcontrib>Szeja, Wies aw</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Biocatalysis and biotransformation</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hahn, Przemys aw</au><au>Kasprzycka, Anna</au><au>Szeja, Wies aw</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of 2-deoxygalactopyranoside derivatives of benzyl alcohols with β-galactosidase from Aspergillus oryzae</atitle><jtitle>Biocatalysis and biotransformation</jtitle><date>2014-12-01</date><risdate>2014</risdate><volume>32</volume><issue>5-6</issue><spage>290</spage><epage>294</epage><pages>290-294</pages><issn>1024-2422</issn><eissn>1029-2446</eissn><abstract>Abstract The stereoselective synthesis of 2-deoxyglycosides is a challenge. Glycosidases are capable of catalyzing the synthesis of glycosidic linkages by the absolute stereoselectivity of the anomeric center. We report on an efficient stereoselective synthesis of benzyl β-D-2-deoxygalactopyranosides in the reaction of galactal with alcohols catalyzed using β-galactosidase from Aspergillus oryzae.</abstract><pub>Informa Healthcare</pub><doi>10.3109/10242422.2014.975216</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1024-2422
ispartof Biocatalysis and biotransformation, 2014-12, Vol.32 (5-6), p.290-294
issn 1024-2422
1029-2446
language eng
recordid cdi_crossref_primary_10_3109_10242422_2014_975216
source Taylor and Francis:Jisc Collections:Taylor and Francis Read and Publish Agreement 2024-2025:Science and Technology Collection (Reading list)
subjects 2-deoxygalactosyl derivatives
Aspergillus oryzae
enzymatic synthesis
β-galactosidase
title Synthesis of 2-deoxygalactopyranoside derivatives of benzyl alcohols with β-galactosidase from Aspergillus oryzae
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T15%3A44%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%202-deoxygalactopyranoside%20derivatives%20of%20benzyl%20alcohols%20with%20%CE%B2-galactosidase%20from%20Aspergillus%20oryzae&rft.jtitle=Biocatalysis%20and%20biotransformation&rft.au=Hahn,%20Przemys%20aw&rft.date=2014-12-01&rft.volume=32&rft.issue=5-6&rft.spage=290&rft.epage=294&rft.pages=290-294&rft.issn=1024-2422&rft.eissn=1029-2446&rft_id=info:doi/10.3109/10242422.2014.975216&rft_dat=%3Cproquest_cross%3E1727674163%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c395t-fba8e868ae0a7d0c5eee92ec8be6b6c32a5ac4b5c260b6dd4b0cb67eeb754c023%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1727674163&rft_id=info:pmid/&rfr_iscdi=true