Influencing mechanisms of a wax layer on the micro-friction behavior of the β-HMX crystal surface

• Published in: Energetic materials frontiers 2022-12, Vol.3 (4), p.248-256
• Main Authors: Li, Hong-tao, Sun, Jie, Sui, He-liang, Chai, Chuan-guo, Li, Bing-hong, Yu, Jia-xin, He, Hong-tu, Yin, Ying
• Format: Article
• Language: English
• Subjects: Lubrication interface; Micro friction behavior; Stick-slip effect; Wax layer; β-HMX crystal
• ISSN: 2666-6472; 2666-6472
• DOI: 10.1016/j.enmf.2022.12.001

This study investigated the influence of the wax layer on the micro-friction behavior of the energetic crystal surface by constructing the lubricating interface between wax and β-HMX crystals. The nano-scratch testing of β-HMX crystals with and without wax coating was conducted under the ramp-loading (0–3.5 ​mN) mode and the constant-loading (0.4 ​mN) mode. The testing results are as follows. Compared with the dry friction of β-HMX crystals without wax coating, wax can significantly improve the contact friction between the energetic crystals and the rigid micro-convex body. The influence of wax on the interface friction highly depends on the external load conditions. Under the ramp-loading mode, the wax layer can greatly reduce the average coefficient of friction (COF) from ∼0.7 (dry friction) to ∼0.2 (lubricating interface) and inhibit COF fluctuation. The inherent mechanism of wax reducing the interface friction works in the following way. Wax can effectively suppress the plowing effect of the rigid micro-convex body on the β-HMX crystal surface and further inhibit the occurrence of brittle fracture and crack defects. The wax layer can also suppress the friction anisotropy of the β-HMX crystal surface, significantly reducing the probability of high COF (>0.4). The distribution probabilities of COF in the range of 0–0.1 and 0–0.3 were 33% and 89%, respectively. The stick-slip effect of the friction behavior was observed under the constant-loading mode, with the COF varying periodically with the sliding distance. These study results can help understand the desensitization mechanisms of wax on the energetic crystal surface at a micro-scale quantitative level and provide a necessary basis for building the friction hot-spot model under dry friction and wax lubrication. The nano-scratch testing of rigid micro-convex scratching on the β-HMX crystal surface was conducted to study the effect of the wax layer on the micro-friction behavior of energetic crystals. Two loading modes of external force were applied. The ramp-loading mode was applied to identify the normal load-dependent elastic-plastic transition and friction coefficient in situ. The constant-loading mode was applied to reveal the evolution of the friction behavior in the wax layer, the wax-crystal interface, and the crystal, respectively. After the nano-scratch testing, the surface morphologies and the anisotropic friction of β-HMX crystals with and without wax-coating were compared. Eventually, two m