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Direct Synthesis of Mn3[Fe(CN)6]2·nH2O Nanosheets as Novel 2D Analog of Prussian Blue and Material for High-Performance Metal-Ion Batteries
Rechargeable metal-ion batteries (RMIBs) are prospective highly effective and low-cost devices for energy storage. Prussian blue analogues (PBAs) have become a subject of significant interest for commercial applications owing to their exceptional specific capacity and broad operational potential win...
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Published in: | Micromachines (Basel) 2023-05, Vol.14 (5), p.1083 |
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description | Rechargeable metal-ion batteries (RMIBs) are prospective highly effective and low-cost devices for energy storage. Prussian blue analogues (PBAs) have become a subject of significant interest for commercial applications owing to their exceptional specific capacity and broad operational potential window as cathode materials for rechargeable metal-ion batteries. However, the limiting factors for its widespread use are its poor electrical conductivity and stability. The present study describes the direct and simple synthesis of 2D nanosheets of MnFCN (Mn3[Fe(CN)6]2·nH2O) on nickel foam (NF) via a successive ionic layer deposition (SILD) method, which provided more ion diffusion and electrochemical conductivity. MnFCN/NF exhibited exceptional cathode performance for RMIBs, delivering a high specific capacity of 1032 F/g at 1 A/g in an aqueous 1M NaOH electrolyte. Additionally, the specific capacitance reached the remarkable levels of 327.5 F/g at 1 A/g and 230 F/g at 0.1 A/g in 1M Na2SO4 and 1M ZnSO4 aqueous solutions, respectively. |
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Prussian blue analogues (PBAs) have become a subject of significant interest for commercial applications owing to their exceptional specific capacity and broad operational potential window as cathode materials for rechargeable metal-ion batteries. However, the limiting factors for its widespread use are its poor electrical conductivity and stability. The present study describes the direct and simple synthesis of 2D nanosheets of MnFCN (Mn3[Fe(CN)6]2·nH2O) on nickel foam (NF) via a successive ionic layer deposition (SILD) method, which provided more ion diffusion and electrochemical conductivity. MnFCN/NF exhibited exceptional cathode performance for RMIBs, delivering a high specific capacity of 1032 F/g at 1 A/g in an aqueous 1M NaOH electrolyte. Additionally, the specific capacitance reached the remarkable levels of 327.5 F/g at 1 A/g and 230 F/g at 0.1 A/g in 1M Na2SO4 and 1M ZnSO4 aqueous solutions, respectively.</description><identifier>ISSN: 2072-666X</identifier><identifier>EISSN: 2072-666X</identifier><identifier>DOI: 10.3390/mi14051083</identifier><identifier>PMID: 37241706</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>2D materials ; Aqueous solutions ; Cathodes ; Communication ; Diffusion layers ; Electrical resistivity ; Electrode materials ; Electrodes ; Electrolytes ; Energy storage ; Hydrochloric acid ; Ion diffusion ; Metal foams ; metal-ion batteries ; MnFCN ; Morphology ; Nanocrystals ; Nanosheets ; Nickel ; Pigments ; Potassium ; Prussian blue analogue ; Reagents ; Rechargeable batteries ; SILD ; Spectrum analysis ; Synthesis ; Thin films ; Zinc</subject><ispartof>Micromachines (Basel), 2023-05, Vol.14 (5), p.1083</ispartof><rights>2023 by the authors. 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Prussian blue analogues (PBAs) have become a subject of significant interest for commercial applications owing to their exceptional specific capacity and broad operational potential window as cathode materials for rechargeable metal-ion batteries. However, the limiting factors for its widespread use are its poor electrical conductivity and stability. The present study describes the direct and simple synthesis of 2D nanosheets of MnFCN (Mn3[Fe(CN)6]2·nH2O) on nickel foam (NF) via a successive ionic layer deposition (SILD) method, which provided more ion diffusion and electrochemical conductivity. MnFCN/NF exhibited exceptional cathode performance for RMIBs, delivering a high specific capacity of 1032 F/g at 1 A/g in an aqueous 1M NaOH electrolyte. 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subjects | 2D materials Aqueous solutions Cathodes Communication Diffusion layers Electrical resistivity Electrode materials Electrodes Electrolytes Energy storage Hydrochloric acid Ion diffusion Metal foams metal-ion batteries MnFCN Morphology Nanocrystals Nanosheets Nickel Pigments Potassium Prussian blue analogue Reagents Rechargeable batteries SILD Spectrum analysis Synthesis Thin films Zinc |
title | Direct Synthesis of Mn3[Fe(CN)6]2·nH2O Nanosheets as Novel 2D Analog of Prussian Blue and Material for High-Performance Metal-Ion Batteries |
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