Mechanical property—processing relations for SiC foams synthesized via polymer particle templating of polycarbosilane

• Published in: International journal of ceramic engineering & science 2024-01, Vol.6 (1), p.n/a
• Main Authors: Kassner, Christopher T., Wadley, Haydn N. G.
• Format: Article
• Language: English
• Subjects: Compressive strength; Crystallization; Diameters; Gas turbine engines; Ligaments; Mechanical properties; Modulus of elasticity; Nanomaterials; Nanoparticles; Plastic foam; polymer precursor; Polymers; Polymethyl methacrylate; porous materials; processing; Pyrolysis; Silicon carbide; Synthesis; Temperature; Thermogravimetric analysis; Viscosity
• ISSN: 2578-3270; 2578-3270
• DOI: 10.1002/ces2.10196

Silicon carbide foams with an average pore diameter of 650 nm and an inter‐pore ligament thickness of 150 nm have been synthesized using spherical polymethylmethacrylate (PMMA) particle templating of a β‐SiC nanoparticle‐loaded polycarbosilane (PCS) preceramic polymer and the effect of crystallization temperature upon their microstructure and mechanical properties investigated. Differential scanning calorimetry and thermogravimetric analysis were used to investigate both the kinetics of PMMA decomposition and the influence of β‐SiC nanoparticles upon the mechanisms of PCS cure, pyrolysis, and partial crystallization. As the crystallization temperature was systematically increased, the inter‐pore ligament structure coarsened and nanopores developed within the ligaments between the β‐SiC nanoparticles. The foam's Young's modulus and compressive strength at first increased with crystallization temperature, reaching a maximum after processing at 1300˚C. However, further increases in temperature resulted in a rapid fall in both foam modulus and compressive strength. To gain insight into the fundamental processes responsible for the overall (macroscale) mechanical properties, models for open/closed cell foams were inverted and used in conjunction with the measured foam density, Young's modulus, and compressive strength to estimate the mechanical properties of the inter‐pore ligaments. This procedure indicated that changes to the ligament properties were responsible for the observed dependence of the foam mechanical properties upon crystallization temperature. Silicon carbide foams with an average pore diameter of 650 nm and an interpore ligament thickness of 150 nm have been synthesized using spherical polymethylmethacrylate particle templating of an SiC nanoparticle‐loaded polycarbosilane preceramic polymer and the effect of crystallization temperature upon their microstructure and mechanical properties investigated. To gain insight into the fundamental processes responsible for the overall (macroscale) mechanical properties, models for open/closed cell foams used together with the measured foam density, Young's modulus, and compressive strength enabled an estimation of the mechanical properties of the interpore ligaments. This procedure indicated that changes to the ligament properties were responsible for the observed dependence of the foam mechanical properties upon crystallization temperature.