A novel activated carbon-based nanocomposite for the removal of bisphenol-A from water via catalytic ozonation: Efficacy and mechanisms

• Published in: Results in Chemistry 2022-01, Vol.4, p.100593, Article 100593
• Main Authors: Pokkiladathu, Hariprasad, Farissi, Salman, Muthukumar, Anbazhagi, Muthuchamy, Muthukumar
• Format: Article
• Language: English
• Subjects: Bisphenol-A; Byproducts; Catalytic Ozonation; Degradation; Nano-bimetallic catalysts; Water
• ISSN: 2211-7156; 2211-7156
• DOI: 10.1016/j.rechem.2022.100593

•Characterization of AC/Bi2O3/V2O5 nanocomposite showed optimal binding of Bi2O3 and V2O5 to the Activated Carbon Surface.•BPA degradation was enhanced by the AC/Bi2O3/V2O5/O3 process compared to O3 process.•O3 radicals got decomposed on the nano-composite bimetallic catalyst surface and formed OH radicals.•OH radicals improved the TOC removal in the AC/Bi2O3/V2O5/O3 process. Concerns have been raised about the increasing number and quantity of contaminants in water resources. For a sustainable future, advances for the elimination of these contaminants of emerging concern (CECs) are important. Advanced oxidation processes (AOPs) such as non-catalytic ozonation and catalytic ozonation, have been shown to be effective in removing dissolved contaminants in water and wastewater. Here, we have used a novel nano-composite bimetallic catalyst (AC/Bi2O3/V2O5) for the removal of 5 mg/L of Bisphenol-A (BPA) from water. The characterization of the bimetallic catalyst using Brunauer Emmet Teller surface area (BET) studies, X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), raman spectra, and dynamic light scattering (DLS) studies showed that it binds to the activated carbon surface and no foreign bodies were found. Fourier transform infra red (FTIR) studies confirm the degradation and the robustness of the catalyst structure. Degradation studies with different variables found pH 8, 500 µg/L catalyst dosage and 60 min treatment time optimal for maximum BPA removal (97 %) and total organic carbon (TOC) removal (68 %). TOC analysis confirmed that catalytic ozonation with the novel catalyst is 32 % more efficient than non-catalytic ozonation. The degradation pathway of BPA was determined using liquid chromatography-mass spectrophotometer/liquid chromatography-quadrupole time of flight- mass spectrophotometer (LC-MS/LC-Q-TOF-MS) studies.