Application of Biochar from Woodchip as Catalyst Support for Biodiesel Production

• Published in: Catalysts 2023-03, Vol.13 (3), p.489
• Main Authors: Azman, Nor Shafinaz, Khairuddin, Nozieana, Tengku Azmi, Tengku Sharifah Marliza, Seenivasagam, Sivasangar, Hassan, Mohd Ali
• Format: Article
• Language: English
• Subjects: Alternative energy; biochar; biodiesel; Biodiesel fuels; Biomass; Carbon; Catalysts; Chemical reactions; Chemical synthesis; Cooking; Diesel engines; Diesel motor; Energy industry; Energy resources; Fatty acids; Field emission; Fossil fuels; Fourier transforms; Gas flow; Global temperature changes; Global warming potential; heterogenous catalysis; Hydrocarbons; Metal oxides; Palm oil; Renewable resources; Roasting; Transesterification; Triglycerides; used cooking oil; Wastewater; Wastewater treatment; wet impregnation; woodchips; Zeolites
• ISSN: 2073-4344; 2073-4344
• DOI: 10.3390/catal13030489

In Asian countries, the primary palm oil producers, used cooking oil (UCO) is the primary feedstock for biodiesel production. It can be converted into an eco-fuel for application in heavy machinery and diesel engine vehicles due to its low carbon emissions and low global warming potential. However, the illegal dumping of UCO containing triglyceride into flowing water bodies (resulting in wastewater treatment and purification complications) has prompted the design of smart UCO collection systems. This study aims to investigate the heterogeneous catalytic performance of biochar as a support catalyst derived from woodchips calcined at 400 °C and 800 °C under nitrogen gas flow. The catalyst was synthesized through the wet impregnation method using two metal oxides (5 wt.%, nickel and molybdenum) via transesterification to enhance the biodiesel yield. High biodiesel yield was obtained through the controlled parameters: 65–95 °C temperature, 10:1 methanol to oil ratio, and 2 h reaction time. The synthesized catalyst was characterized through X-ray Diffraction (XRD) and Field Emission Scanning Electron (FESEM). The biodiesel production was confirmed by Fourier Transform Infra-Red (FTIR) Spectroscopy. The results showed that the highest biodiesel yield was produced by the catalyst calcined at 800 °C, which shows a consistent trend in the yields obtained at temperatures in the order 75–85–95–65 °C. In conclusion, calcination at 800 °C resulted in a higher yield (74.66%) and catalyst reusability (≥5 cycles).