Kinetic and isotherm modeling for acid blue 113 dye adsorption onto low-cost nutraceutical industrial fenugreek seed spent

• Published in: Applied water science 2020-02, Vol.10 (2), p.1-16, Article 58
• Main Authors: Dhaif-Allah, Mohammed A. H., Taqui, Syed Noeman, Syed, Usman Taqui, Syed, Akheel Ahmed
• Format: Article
• Language: English
• Subjects: Acid blue 113; Adsorbents; Adsorption; Adsorption isotherm; Analytical methods; ANOVA; Aquatic Pollution; Aqueous solutions; Comparative Law; Design of experiments; Dyes; Earth and Environmental Science; Earth Sciences; Electron microscopy; Enthalpy; Entropy; Experimental design; Fenugreek; Fourier analysis; Fourier transforms; Free energy; Functional foods & nutraceuticals; Gibbs free energy; Hydrogeology; Industrial and Production Engineering; Industrial effluents; Industrial wastewater; Infrared spectroscopy; International & Foreign Law; Isotherms; Kinetics; Low cost; Mathematical models; Molecular diffusion; Nanotechnology; Nutraceutical industrial fenugreek seed spent; Original Article; Private International Law; Process parameters; Scaling; Scanning electron microscopy; Trigonella foenum-graecum; Variance analysis; Waste Water Technology; Water Industry/Water Technologies; Water Management; Water Pollution Control
• ISSN: 2190-5487; 2190-5495
• DOI: 10.1007/s13201-020-1141-3

The present study reports about the use of fenugreek seed spent as a new and efficient biosorbent for the removal of acid blue 113 dye from aqueous media and textile industrial effluent. The spent is a low-cost by-product of nutraceutical industry. The effects of various process parameters of adsorption, such as pH, initial dye concentration, adsorbent dose, adsorbent particle size, contact time and temperature onto nutraceutical industrial fenugreek seed spent (NIFGS) have been studied. Four numbers of two-parameter and six numbers of three-parameter isotherm models were used in the analysis of adsorption equilibrium data. Kinetic studies data conformed to pseudo-second-order model. Molecular diffusion studies were carried out using Weber–Morris, Dumwald–Wagner and film diffusion models. Change in enthalpy (Δ H °), entropy change (Δ S °) and Gibbs free energy change (Δ G °) of adsorption system indicated that the process is physisorption. Scanning electron microscopy, Fourier transform infrared spectroscopy and point of zero charge were used in characterizing the adsorbent. Fractional factorial experimental design and analysis of variance along with statistically developed model for adsorption helped to predict for a maximum adsorption of 661.5 mg g −1 using NIFGS. Application of NIFGS to textile industrial effluent and scaling up of the experimental process by three orders gave encouraging results.