Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium

The asymmetric aza-Diels-Alder reaction of chiral imines with Danishefsky's diene in chiral ionic liquids provides the corresponding cycloadduct with moderate to high diastereoselectivity. The reaction has proved to perform better at room temperature in ionic liquids without either Lewis acid c...

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Bibliographic Details
Published in:Beilstein journal of organic chemistry 2006-09, Vol.2 (1), p.18-18
Main Authors: Pégot, Bruce, Nguyen, Van Buu Olivier, Gori, Didier, Vo-Thanh, Giang
Format: Article
Language:English
Subjects:
Chemistry
Preliminary Communication
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Summary:The asymmetric aza-Diels-Alder reaction of chiral imines with Danishefsky's diene in chiral ionic liquids provides the corresponding cycloadduct with moderate to high diastereoselectivity. The reaction has proved to perform better at room temperature in ionic liquids without either Lewis acid catalyst or organic solvent. Chiral ionic liquids are recycled while their efficiency is preserved.
ISSN:1860-5397
1860-5397
DOI:10.1186/1860-5397-2-18