Portable, low-cost samplers for distributed sampling of atmospheric gases

• Published in: Atmospheric measurement techniques 2023-10, Vol.16 (19), p.4681-4692
• Main Authors: Hurley, James F, Caceres, Alejandra, McGlynn, Deborah F, Tovillo, Mary E, Pinar, Suzanne, Schürch, Roger, Onufrieva, Ksenia, Isaacman-VanWertz, Gabriel
• Format: Article
• Language: English
• Subjects: Air pollution; Analytical chemistry; Atmospheric gases; Atmospheric ozone; Cartridges; Chromatography; Computer networks; Detection; Environmental protection; Gas sampling; Gases; Hazardous air pollutants; Hazardous materials; Indoor environments; Instrumentation; Locating; Low cost; Mathematical analysis; Measuring instruments; Mixing ratio; Natural gas; Organic compounds; Oxidants; Oxidizing agents; Ozone; Particulate matter; Pollution control equipment; Portable equipment; Samplers; Sampling; Scrubbers; Sorbents; Suspended particulate matter; Temporal distribution; Variability; VOCs; Volatile organic compounds
• ISSN: 1867-8548; 1867-1381; 1867-8548
• DOI: 10.5194/amt-16-4681-2023

Volatile organic compounds (VOCs) contribute to air pollution both directly, as hazardous gases, and through their reactions with common atmospheric oxidants to produce ozone, particulate matter, and other hazardous air pollutants. There are enormous ranges of structures and reaction rates among VOCs, and there is consequently a need to accurately characterize the spatial and temporal distribution of individual identified compounds. Current VOC measurements are often made with complex, expensive instrumentation that provides high chemical detail but is limited in its portability and requires high expense (e.g., mobile labs) for spatially resolved measurements. Alternatively, periodic collection of samples on cartridges is inexpensive but demands significant operator interaction that can limit possibilities for time-resolved measurements or distributed measurements across a spatial area. Thus, there is a need for simple, portable devices that can sample with limited operator presence to enable temporally and/or spatially resolved measurements. In this work, we describe new portable and programmable VOC samplers that enable simultaneous collection of samples across a spatially distributed network, validate their reproducibility, and demonstrate their utility. Validation experiments confirmed high precision between samplers as well as the ability of miniature ozone scrubbers to preserve reactive analytes collected on commercially available adsorbent gas sampling cartridges, supporting simultaneous field deployment across multiple locations. In indoor environments, 24 h integrated samples demonstrate observable day-to-day variability, as well as variability across very short spatial scales (meters). The utility of the samplers was further demonstrated by locating outdoor point sources of analytes through the development of a new mapping approach that employs a group of the portable samplers and back-projection techniques to assess a sampling area with higher resolution than stationary sampling. As with all gas sampling, the limits of detection depend on sampling times and the properties of sorbents and analytes. The limit of detection of the analytical system used in this work is on the order of nanograms, corresponding to mixing ratios of 1–10 pptv after 1 h of sampling at the programmable flow rate of 50–250 sccm enabled by the developed system. The portable VOC samplers described and validated here provide a simple, low-cost sampling solution for spatially