Ultra-Efficient and Cost-Effective Platinum Nanomembrane Electrocatalyst for Sustainable Hydrogen Production

• Published in: Nano-micro letters 2024-12, Vol.16 (1), p.108-16, Article 108
• Main Authors: Gao, Xiang, Dai, Shicheng, Teng, Yun, Wang, Qing, Zhang, Zhibo, Yang, Ziyin, Park, Minhyuk, Wang, Hang, Jia, Zhe, Wang, Yunjiang, Yang, Yong
• Format: Article
• Language: English
• Subjects: Catalysts; Clean energy; Electrocatalysis; Electrocatalysts; Engineering; Foils; Heterogeneous strain; Hydrogen; Hydrogen evolution reaction; Hydrogen evolution reactions; Hydrogen production; Lattice design; Lattice distortion; Nanoscale Science and Technology; Nanotechnology; Nanotechnology and Microengineering; Noble metals; Percolation; Platinum; Strain
• ISSN: 2311-6706; 2150-5551; 2150-5551
• DOI: 10.1007/s40820-024-01324-5

Highlights A percolating network of distorted 2D Pt nanomembranes was synthesized by polymer surface buckling-enabled exfoliation for hydrogen evolution reaction. The 2D Pt nanomembrane enabled important technological applications for its high efficiency, low costs, and good stability, making it potential alternative to commercial Pt/C. Our 2D Pt nanomembranes offer insights into a new mechanism for efficient catalyst design strategy: lattice distortion-induced heterogeneous strain. Hydrogen production through hydrogen evolution reaction (HER) offers a promising solution to combat climate change by replacing fossil fuels with clean energy sources. However, the widespread adoption of efficient electrocatalysts, such as platinum (Pt), has been hindered by their high cost. In this study, we developed an easy-to-implement method to create ultrathin Pt nanomembranes, which catalyze HER at a cost significantly lower than commercial Pt/C and comparable to non-noble metal electrocatalysts. These Pt nanomembranes consist of highly distorted Pt nanocrystals and exhibit a heterogeneous elastic strain field, a characteristic rarely seen in conventional crystals. This unique feature results in significantly higher electrocatalytic efficiency than various forms of Pt electrocatalysts, including Pt/C, Pt foils, and numerous Pt single-atom or single-cluster catalysts. Our research offers a promising approach to develop highly efficient and cost-effective low-dimensional electrocatalysts for sustainable hydrogen production, potentially addressing the challenges posed by the climate crisis.